KHAEMENES ACADEMY · CHEMISTRY 11 · WEEK 23 · DAY 03

Enthalpy & Reaction-Energy Accounting

Interpret reaction enthalpy as a system-level energy change at constant pressure.

Safety boundary

Use virtual calorimetry or teacher-supervised water-based calorimetry only. No unsupervised flames, reactive chemicals, or improvised heat sources.

Explicit chemistry instruction

Enthalpy change ΔH is a useful constant-pressure energy-accounting quantity.

Negative ΔH corresponds to exothermic reaction under the standard convention; positive ΔH corresponds to endothermic.

A reaction-energy diagram separates overall ΔH from activation-energy barriers.

Vocabulary: enthalpy; ΔH; reaction coordinate; activation energy; state function.

Worked example

If products lie 40 kJ/mol below reactants on an energy diagram, ΔH≈−40 kJ/mol.

Guided question

How can a reaction have negative ΔH but still require activation energy?

Independent work

  1. Interpret three reaction-energy diagrams.
  2. Calculate ΔH from relative energy levels.
  3. Distinguish ΔH from activation energy.

Misconception check

Exothermic does not mean barrier-free or instantaneous.

Formative check

What does ΔH compare?

Reveal response

The enthalpy of products with reactants.

Mentor evidence conference

Ask Archaemenes to audit signs, units, system boundaries, and whether the evidence supports the energy claim.

Teacher guidance

Foundation: Read energy diagrams.

Core: Connect calorimetry with reaction enthalpy.

Extended: Compare thermodynamic favorability with kinetic barriers.