KHAEMENES ACADEMY · CHEMISTRY 11 · WEEK 32 · DAY 05

Free-Energy Synthesis

Integrate enthalpy, entropy, temperature, equilibrium, and kinetics without conflating them.

Safety boundary

Use supplied graphs and calculations only. No new reactive chemistry is required.

Explicit chemistry instruction

Thermodynamic favorability depends on ΔG; equilibrium occurs where net driving force vanishes; kinetics controls rate.

Temperature can shift favorability because it scales the entropy term.

A complete explanation states conditions and keeps direction separate from speed.

Vocabulary: thermodynamics; equilibrium; kinetics; temperature; driving force.

Worked example

A reaction can have ΔG<0 yet proceed slowly if the activation barrier is large.

Guided question

Write a five-sentence explanation separating ΔG, K/equilibrium, and activation energy.

Independent work

  1. Solve one ΔG problem.
  2. Interpret one temperature effect.
  3. Contrast rate with direction.
  4. Record one correction.

Spiral retrieval bridge

  1. From Week 25: separate entropy, enthalpy, and kinetics.
  2. From Week 24: distinguish state function from pathway.
  3. From Week 27: identify which perturbation changes an equilibrium constant.

Misconception check

Thermodynamic favorability and reaction speed are different dimensions of behavior.

Formative check

Which model addresses how fast a reaction occurs?

Reveal response

Kinetics and activation-energy models.

Mentor evidence conference

Ask Archaemenes to audit signs, units, thermodynamic conditions, and whether rate/direction are being kept distinct.

Teacher guidance

Foundation: Use a concept-separation table.

Core: Integrate ΔG with equilibrium.

Extended: Connect thermodynamics and kinetics quantitatively.